First impressions can definitely set the tone of a relationship, and 'The Twilight Saga: New Moon' star Anna Kendrick tells ET what it was like to work with George Clooney on the upcoming 'Up in the Air,' in theaters this December.

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Oprah Winfrey and George Clooney are among the A-list guests who’ve visited the White House since President Barack Obama and his family moved in last January.

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Superstar George Clooney and new girlfriend, Italian model Elisabetta Canalis, have been sending photogs into a tizzy by rocking the red carpet all over Europe. The dashing duo is on a whirlwind tour to promote the Oscar winner's upcoming three films -- 'Up in the Air,' 'The Men Who Stare at Goats' and 'Fantastic Mr. Fox.' Take a look at dozens of glamorous pics of Hollywood's newest "It" couple steaming up the red carpet!

George Clooney walked the red carpet at the London premiere of his highly anticipated film, 'The Men Who Stare at Goats,' after holding a press conference with costar Kevin Spacey, where he dished about the new film.

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Just one day after heating up the red carpet at the premiere of his animated film 'Fantastic Mr. Fox,' George Clooney once again stepped out with foxy Italian actress Elisabetta Canalis in London at the Thursday premiere of his highly anticipated film, 'The Men Who Stare at Goats.'

Take a look through ET's gallery of the sizzlin' couple burning up the red carpet -- and click here to see snapshots of the duo from Wednesday night's event.

George Clooney is headed back to theaters in a wacky new role in 'The Men Who Stare At Goats,' and ET has a sneak peek.

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George Clooney is headed back to theaters in a wacky new role in 'The Men Who Stare At Goats,' and ET has a sneak peek.

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George Clooney and the foxy Elisabetta Canalis set the shutterbugs ablaze Wednesday at the London premiere of his new animated film ‘Fantastic Mr. Fox’ at the Times BFI London Film Festival. Take a look through ET’s gallery of the sizzlin' couple heating up the red carpet -- and click here to see snapshots of them together at the 66th Venice Film Festival in Italy last month.

Also on hand for Wednesday’s big event: Bill Murray and Jason Schwartzman, who both lend their voices to the film, and former supermodel Cindy Crawford!

ET's Mary Hart presented actress Anna Kendrick with the Palm Springs International Film Festival Rising Star Award, and the actress opened up about working alongside George Clooney in her new film 'Up in the Air' and about her role in the wildly popular 'Twilight' film franchise.

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Matt Damon and director Steven Soderbergh premiered their new movie, ‘The Informant!,’ in NYC on Tuesday night, and Matt opened up to ET about his memories of the late Patrick Swayze.

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Still nursing an injured hand, a solo George Clooney heated up the red carpet at the Toronto International Film Fest this weekend in support of two of his films coming out this fall -- 'The Men Who Stare At Goats' and 'Up in the Air' -- and ET was there!

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Emmy winner and "My Life on the D-List" star Kathy Griffin opened up to ET's Mark Steines about her celebrity lovers and a divorce from her husband that she calls "devastating."

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Mr. Charisma, aka George Clooney, has been melting hearts all over the world ever since he first picked up a scalpel on "ER" Now, the super celeb is only worrying about one heart -- that of Italian actress and model Elisabetta Canalis. Earlier today, the sizzlin' new couple took to the red carpet in style at the 66th Venice Film Festival in Italy. Watch the two lovebirds as they coo and canoodle with each other at the festival's premiere of George's new film, 'The Men Who Stare at Goats.'

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Hunky actor George Clooney arrives at the Venice Film Festival with Italian actress and model Elisabetta Canalis.

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George Clooney was injured in an accident in Lake Como, Italy. Read on for details.

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