The Emmy-nominated TV personality glowed in a shimmery gold Monique Lhullier gown, which she paired with Norman Silverman jewelry and a black Rauwolf clutch.
Deeley walked the carpet with her husband of nearly three years, comedian Patrick Kielty, and the two could not have been more delightful, cracking up in front of photographers as they stood arm-in-arm.
Deeley, 38, and Kielty, 44, spent the morning getting their energy up for the awards show, prepping with a breakfast of eggs benedict and plenty of toast and bacon amongst their plates of sides at Cecconi's West Hollywood.
The English actress announced she was expecting her and Kielty's first child earlier this month. "Exciting news... Paddy and I are so happy to be expecting our first child in the spring ... Lucky us," she tweeted on Sept. 3.