Last year, Entertainment Tonight named him "most likely to cross over into Hollywood" after his NFL career. Now, hunky New England Patriots QB Tom Brady talks exclusively to ET's Kevin Frazier about a possible high-profile project with Jennifer Aniston!

In his first TV interview since his season-ending knee injury last fall, Tom invites Kevin behind-the-scenes of his latest ad campaign for SmartWater, a thirst-quenching beverage that Jennifer Aniston also endorses. This makes Kevin wonder: Might Tom and Jen eventually star together in a SmartWater ad?

"They've [SmartWater] talked about that for over a year now," Tom dishes. "I'm always up for anything. I think that would be a fun experience for us."

Click the video for more with the dreamy NFL star, including his thoughts on the Obama family!