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Eight couples donned their country best as week six of the Dancing with the Stars: All Stars competition kicked off Monday night.

Video: Melissa Rycroft Exposes Her 'DWTS' Tango Trick

Little Big Town and Big & Rich lent their Southern stylings to the show as two All-Star dancing duos fancy footed their way to the top of the leaderboard.

Sabrina Bryan and partner Louis Van Amstel took home the first perfect score of the night with a touching Rumba inspired by the former Cheetah Girl's past relationship with a drug-addicted ex.

Apolo Anton Ohno and partner Karina Smirnoff snagged the second and last 30 on Monday with a spectacular Viennese Waltz that wowed the judges to no end.

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With 29.5 points, Melissa Rycroft and partner Tony Dovolani took a close third with their Viennese Waltz, while Shawn Johnson and Derek Hough nipped at their heels with 28 points for their Kenny Chesney-inspired Cha Cha Cha.

Gilles Marini and partner Peta Murgatroyd's lively Cha Cha Cha came in neck-and-neck with Kirstie Alley and Maksim Chmerkovskiy's Rumba which earned a combined score of 27.5, Alley's best of the All-Star competition.

Kelly Monaco and partner Val Chmerkovskiy rounded out the bottom with their Tango, choreographed to Carrie Underwood's Good Girl, while Emmitt Smith and Cheryl Burke were the bottom scorers of the night with 26.5 points earned for their southern-style Foxtrot.

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Keep it tuned to ABC tomorrow night for week six eliminations!