Just call Blake Lively the new queen of the red carpet.

The always fashionable actress exceeded any style expectations at the Age of Adaline premiere in New York City on Sunday, where she had jaws dropping in a glamorous red lace Monique Lhuillier gown. The showstopping designer number featured a curve-hugging bodice and a dramatic feathery train, which the 27-year-old new mom pulled off to perfection. A playful bedazzled Judith Leiber Couture fish-shaped clutch and sideswept waves completed her dazzling look.

PHOTOS: Take a Look Back at Blake Lively's Amazing Maternity Style

"Workin Emoji Chic," she Instagrammed about her cute clutch. "It's the new thing. Watch out Norm Core."

Blake also didn't disappoint at the premiere's afterparty, where she rocked a daring Monique Lhuillier sheer star jumpsuit under an unconventional black coat.

She later showed off her second quirky purse of the night on Instagram.

With Blake's stunning looks last night in NYC, her husband Ryan Reynolds couldn't help but get a little jealous of her Age of Adaline co-star Michiel Huisman.

"Uh... I can HEAR you," he joked on Twitter, after Lionsgate called the two "the perfect pair."

Perhaps it's only payback -- who could forget Ryan gazing lovingly at Helen Mirren at the Woman in Gold premiere earlier this month, which Blake hilariously didn't fail to notice.

"Should I be concerned that my husband's never looked at me this way?..." she joked.

NEWS: Blake Lively Looks Even Better Post-Baby in $500 Jeans

ET recently caught up with Blake, when she dished that she's been saving up clothes for her lucky daughter James since she was 16 years old! Watch below:

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