Sometimes people just don't click...

While Kylie Jenner, Blake Lively and Ryan Reynolds may have all slayed the Met Gala in the wardrobe department on Monday, their fashion fire-ness didn't seem to help them strike up a bond, as the Keeping Up With the Kardashians star was spotted seeming totally disinterested in the power couple seated to her right.

2017 Met Gala: Red Carpet Arrivals

The 19-year-old reality star was disengaged from Lively and Reynolds, texting and looking away while the pair laughed and struck up conversations with other guests, including Chrissy Teigen and John Legend.

Well, guess that's the thing with chemistry -- you really can't force it!

WATCH: Kim Kardashian Attends 2017 Met Gala Solo, In A Demure Look And No Jewelry!

Thankfully, Jenner appeared to be in higher spirits when interacting with other attendees, including fashion designer Olivier Rousteing and her sister, Kendall, who rocked a very bold, sheer-booty La Perla look.

WATCH: Kendall Jenner Shows Off Bare Butt in Sheer Dress at the Met Gala -- See the Pics!

Meanwhile, Jenner's own style basically shut down the whole event, as she rocked a stunning, shiny Versace gown!

Watch the video below for more on the look.

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