Ahhh, one of the most talked-about celebrity divorces in history. It seemed like the perfect match when super star Brad Pitt married America's sweetheart Jennifer Aniston in 2000. They announced their divorce four and a half years later in 2005, when Brad fell for Angelina Jolie on the set of 'Mr. & Mrs. Smith.' Nowadays, Brad and Angelina seem content with their six children, and Jennifer is said to be in a hot new romance with Justin Theroux.