Fresh off their July 1 nuptials, the couple was working together on the set of the Let Me Go music video. The 38-year-old Nickelback frontman assisted his bride, 29, on the duet, which is featured on the album, Avril Lavigne, in stores November 5.
Avril described working on the video as "super last minute."
"A few days ago we all just decided [to have] Let Me Go be the next single," she said. "I was really happy about it because it's a ballad and we're coming up on the holidays and it's our song that we did together. It's also the first song that we wrote together."
Watch the video to see Avril and Chad play ET Canada's revealing "Newlywed Game."