Jolie started working as a model when she was a teenager after experiencing her first on-screen role at the age of five with her father, Jon Voight, in Lookin' To Get Out.
During this photoshoot, she had not been in a relationship since her early teens, but after meeting and falling for her Hackers co-star Johnny Lee Miller in 1995, she married him in 1996. They divorced three years later. She then married her Pushing Tin co-star Billy Bob Thornton in 2000 and divorced him in 2003 before meeting her now-husband Brad Pitt.
Since these sexy snaps were taken, Jolie has obviously managed to accomplish a lot. In addition to winning an Oscar for her supporting work in 1999's Girl Interrupted, she has become a respected director, a mother to six wonderful kids as well as a special envoy to the United Nations.
And while her life has certainly changed since 1995, there's no doubt the gal could still pull off the same model look all these years later!