In a series of Instagram shots, the 27-year-old superstar strikes a pose in her new kicks, while a shirtless Scott (with Puma underwear peeking out from beneath his black leather pants) bows his head behind her.
According to several posts on @badgalriri's page, her new shoe is called The Creeper and the stunning black-and-white campaign was shot by New York-based fashion photographer Tom Munro. The suede sneaker is now available for pre-order.
The promo comes just hours after Rihanna declared that she is still living the single life with a NSFW Instagram post, reading: "'Omg why are you still single?' - cos I'm a c**t."
Though Rihanna and Scott have been hooking up in recent weeks, as ET previously reported, the pair are not yet an official item.
"They are not exclusive, but it could become that," a source told ET. "They are both enjoying time together." The two were spotted packing on the PDA at Rih's star-studded New York Fashion Week Block Party on Sept. 10. They "were all over each other," one eyewitness said.