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Before the ceremony, they made an appearance on the red carpet. Rita, 59, stunned in a gilded, embroidered dress, which she paired with a long gold necklace, strappy black-and-tan heels, and black clutch, while Tom, 60, looked sharp in a black suit and matching tie.
Not only did they look fantastic, there was also plenty of adorable PDA. The Sully star sweetly kissing his wife's hand...
... and the duo walked hand-in-hand down the carpet.