Affleck is nominated this year for Best Actor in a Drama Motion Picture for his role in Manchester by the Sea, while Brosnan and Bening are both former nominees. Bening won Best Actress in a Musical or Comedy in 2011 for The Kids Are All Right, and in 2005 for Being Julia.
Affleck, Brosnan, Foster and Bening will also be joined on stage by Sylvester Stallone's three daughters, Sophia, 20, Sistine, 18, and Scarlet, 14, who were named Miss Golden Globe 2017 by the Hollywood Press Association.
ET caught up with the girls on Wednesday, who dished all about their preparations for the big day.
"I'm just hoping I don't trip when I'm walking on stage," Sophia confessed.
"[Our heels] are comfortable enough to where we don't have to fall, but knowing us, we'll probably fall," Scarlet joked, adding that their parents, Stallone and mom Jennifer Flavin, are more nervous than they are.
"They're giving us so much advice, and they're just worried if we mess up or trip," she said.
Jimmy Fallon will host the 74th annual Golden Globe Awards airing live on Sunday, Jan. 8, at 8 p.m. on NBC.
See more from ET's interview with the Stallone sisters in the video below.