EXCLUSIVE: Melissa Benoist and Her Real-Life Husband Blake Jenner Are Too Cute in This 'Supergirl' Sneak Peek!

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There's something (or should we say, someone?) super cute coming to Supergirl!

On Monday's all-new episode of CBS's high-flying drama, Melissa Benoist's real-life husband, Blake Jenner, is headed to National City.

Only ETonline has your exclusive sneak peek at the couple's first time back together on the small screen -- and let's just say, it doesn't take super powers to sense their undeniable chemistry!

WATCH: Melissa Benoist Gives Girl Scouts a Tour of the 'Supergirl' Set


Jenner is joining the series as Adam Foster, the estranged son of Kara's (Benoist) no-nonsense boss, Cat Grant (Calista Flockhart).

To make this martial crossover even sweeter, Jenner's multi-episode role is also the soon-to-be love interest of Kara. Swoon!

In our first look scene above, the former Glee co-stars -- who tied the knot in spring of 2015 -- share an adorably awkward scene as Kara tries to convince Adam to give his mom another chance.

airs Mondays at 8 p.m. ET/PT on CBS.

Need even more Supergirl secrets? Press play on the video below to get the scoop from Melissa Benoist about how she wants to be a positive role model for girls everywhere.