The actor was visibly shocked after learning his close friends have split.
The singer is mourning the end of Brangelina along with the rest of the world.
'This is the first I've heard of it,' a clearly shocked Clooney replied to the news.
Here's a look at when the parents of six were still an item.
A new promo for Pitt and Cotillard's World War II spy thriller was released one day after Angelina Jolie filed for divorce from the star.
Can't we let Jen live her life?!
The actress is asking for full physical custody of their children.
After two years of marriage, Angelina Jolie has filed for divorce, ET can confirm.
ET is looking back at the estranged couple in happier times.
Following their divorce, ET is taking you back to where it all started.
Here are 12 times the two were a perfect match, style wise.
The couple doesn't appear to have a pre-nuptial agreement, which could make things complicated when it comes to dividing their assets.
Angelina Jolie filed for divorce from Brad Pitt after two years of marriage.
The would-be couple got candid with ET just before their action comedy hit theaters in 2005.
