Jolie posed for photos with Zahara, 12; Shiloh, 11; Vivienne, 9, and Knox, 9, as they arrived at the screening and walked from their SUV to the red carpet press line, where the kids smiled for the camera like seasoned pros.
Jolie and her children posed alongside Nora Twomey, director of The Breadwinner, and the animated film's star, Saara Chaudry.
Jolie, whose production company co-financed and developed The Breadwinner, was also joined by Loung Ung, a Cambodian-born human rights activist who has been working closely with Jolie on the adaptation of her harrowing childhood memoir, First They Killed My Father.
The Breadwinner, based on the best-selling novel of the same name by Deborah Ellis, tells the story of a young girl in Taliban-controlled Afghanistan who is forced to dress as a man to support her family after her father is arrested and taken away. The Breadwinner hits theaters Nov. 17.